\documentclass{jarticle}
\usepackage{multirow,graphicx}

\begin{document}

\begin{table}[htbp]
\begin{tabular}{|p{3cm}|c|c|c|}\hline
\multicolumn{1}{|c|}{\multirow{3}{5pt}{\begin{rotatebox}{90}{$\xi=1$}\end{rotatebox}}}&111&121&131\\
                                                                &112&122&132\\
                                                                &113&124&133\\
\hline
\multicolumn{1}{|c|}{\multirow{3}{5pt}{\begin{rotatebox}{90}{$\xi=2$}\end{rotatebox}}}&211&221&231\\
                                                                &212&222&232\\
                                                                &213&224&233\\
\hline
\end{tabular}
\end{table}


\end{document}
